81736-91-6

Basic information

• Product Name: μ-(4,4'-bipyridine)-bis[(phthalocyaninato)cobalt(II)]*0.5C6H5Cl
• CAS NO: 81736-91-6
• Molecular Weight: 1355.52
• Mol File: 81736-91-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: μ-(4,4'-bipyridine)-bis[(phthalocyaninato)cobalt(II)]*0.5C6H5Cl(CAS DataBase Reference)
• NIST Chemistry Reference: μ-(4,4'-bipyridine)-bis[(phthalocyaninato)cobalt(II)]*0.5C6H5Cl(81736-91-6)
• EPA Substance Registry System: μ-(4,4'-bipyridine)-bis[(phthalocyaninato)cobalt(II)]*0.5C6H5Cl(81736-91-6)

Safety Data

• Hazardous Substances Data: 81736-91-6(Hazardous Substances Data)

Upstream product

• 553-26-4 4,4'-bipyridine 
• 3317-67-7 cobalt(II) phthalocyanine 

Relevant articles and documents

Synthesis and Properties of (Phtalocyaninato)cobalt(II) Adducts with Nitrogen Bases

(α-) and (β-phtalocyaninato)cobalt(II) (PcCo) are treated with ligands L = pyrazine (pyz), 4-methylpyrazine (4-mepyz), pyridine (py), pyridine-d5 (py-d5), 4,4'-bipyridine (bpy), and n-butylamine (bu).The PcCo adducts PcCoL obtained (L = pyz, mepyz, me2pyz, Clpyz, py, py-d5, bu); PcCo-L-CoPc (L = bpy), n (L = pyz); PcCoL2 (L = pyz, py py-d5, pip, bpy), are characterized by ESR spectroscopy, thermal and magnetic measurements.Pentacoordinated complexes PcCoL are formed preferentially.Hexacoordinated complexes PcCoL2 with L = py, 4-mepy, bpy, pyz, piperidine (pip) are only formed at a high ligand concentration.While the polymer n was isolated as a stable compound, attempts to obtain n were unsuccessful.With 1,4-diazabicyclooctane (dabco), a strong ?-donor ligand, n is easily formed.In addition, the reaction of PcCo with 1,6-naphthyridine (naph), benzyl isocyanide (bzNC), and 1,4-diisocyanobenzene (dib) was also investigated.