81744-40-3Relevant academic research and scientific papers
METALLA IV-b-PHOSPHOLANNES II-METALLA-2 (OXA-, THIA- ou AZA-)-3 PHOSPHOLANNES
Andriamizaka, J. D.,Escudie, J.,Couret, C.,Satge, J.
, p. 279 - 286 (2007/10/02)
2-sila-, germa- or stanna- 3-(oxa-, thia- or aza-) phospholanes have been synthesized by reactions of dihalometalla-IV-b compounds with dilithiated β-phosphorus alcohols, thiols or amines HYCH2CH2P(H)Ph (Y=O, S, NMe).Germa- and stanna- heterocycles can also be obtained from germyl- or stannyldiamines and the same β-phosphorus alcohols, thiols or amines. 2-sila 3-(oxa- or thia-) phospholanes are of particular interest for their decomposition reaction leading to silanone or silathione and phosphirane.
