81767-79-5

Basic information

• Product Name: {NiCl₂((C₆H₅)2PCH₂P(C₆H₅)2)2}
• CAS NO: 81767-79-5
• Molecular Weight: 898.39
• Mol File: 81767-79-5.mol

Chemical Properties

• CAS DataBase Reference: {NiCl₂((C₆H₅)2PCH₂P(C₆H₅)2)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {NiCl₂((C₆H₅)2PCH₂P(C₆H₅)2)2}(81767-79-5)
• EPA Substance Registry System: {NiCl₂((C₆H₅)2PCH₂P(C₆H₅)2)2}(81767-79-5)

Safety Data

• Hazardous Substances Data: 81767-79-5(Hazardous Substances Data)

Upstream product

• 2071-20-7 bis-diphenylphosphinomethane 

Downstream Products

• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 106251-27-8 tricarbonylbis(bis(diphenylphosphino)methane)dinickel⁽⁰⁾ 
• 113894-20-5 (1η-dpm)2Ni(CO)2 

Relevant articles and documents

Ditertiary phosphine complexes of nickel. Spectral, magnetic, and proton resonance studies. A planar-tetrahedral equilibrium

A number of complexes of nickel in oxidation states 0, II, and III with the ditertiary phosphines (C6H5)2P(CH2)nP(C 6H5)2 (n = 1, 2, or 3) are reported and studied by spectral and magnetic methods. In solution in organic solvents complexes of the type Ni[(C6H5)2P(CH2)nP(C 6H5)2]X2 where X = Br or I and n = 2 remain diamagnetic. The analogous complexes with n = 3 show a square-planar (diamagnetic)-tetrahedral (paramagnetic) equilibrium in solution. Isotropic proton magnetic resonance shifts were observed in these systems and thermodynamic parameters for the equilibrium were obtained from the temperature dependences of these shifts. The epr spectrum of polycrystalline Ni[(C6H5)2P(CH2)3P(C 6H5)2]Br3 shows an isotropic signal at g = 2.218.