81780-06-5Relevant academic research and scientific papers
Further Comments on One-electron Oxidation versus Nitrosyl Complex Formation during the Reactions of the Nitrosyl Cation with Metal Carbonyl Derivatives
Ashford, Paul K.,Baker, Paul K.,Connelly, Neil G.,Kelly, Raymond L.,Woodley, Valerie A.
, p. 477 - 480 (2007/10/02)
The cation (1+) reacts with to give (1+)(2) or, when NO is removed from the reaction mixture, (1+) (3; M = Cr).A modification is therefore made to the mechanism previously proposed for the reactions of (1+) with metal carbonyl derivatives, n>, such that the intermediate adduct n(NO)>(1+) is in equilibrium with n>(1+) and NO radicals.The isolation of the acid-base adducts (1+) (4; M = Mo or W, L-L = dppe or dppm), from the reaction of (1) with Ag(1+) ions, is indirect evidence for the formation of seven-co-ordinate intermediates, (1+), in the reactions between (1) and (1+).
