81787-37-3Relevant academic research and scientific papers
Unprecedented noncatalyzed anti-carbozincation of diethyl acetylenedicarboxylate through alkylzinc group radical transfer
Maury, Julien,Feray, Laurence,Bertrand, Michele P.
supporting information; experimental part, p. 1884 - 1887 (2011/05/15)
The radical carbozincation of diethyl acetylenedicarboxylate, performed at room temperature in the presence of air, leads to fumaric derivatives through a selective alkylzinc group radical transfer controlled by coordination. The total trans stereocontrol
