81850-98-8Relevant academic research and scientific papers
A route to benzylic arylsulfoxides from β-ketosulfoxides
Chang, Meng-Yang,Cheng, Yu-Chieh,Chan, Chieh-Kai
, p. 4068 - 4075 (2016/07/06)
The K2CO3-mediated benzylation of β-ketosulfoxides 4 with 2.0?equiv of benzylic halides 5 affords benzylic arylsulfoxides 6 in moderate yields along with trace amounts of chalcones 7. The products 6 are assumed to form in situ intermediates of sulfenate anions from β-ketosulfoxides which are commonly involved in carbon–sulfur bond formation. A plausible mechanism has been proposed.
The Preparation of Trichloro(phenyl 2-pyridylmethyl sulphoxide)gold(III) and the Kinetics and Equilibria of its Formation and Subsequent Reactions
Cattalini, Lucio,Chessa, Gavino,Marangoni, Giampaolo,Pitteri, Bruno,Tobe, Martin L.
, p. 2091 - 2094 (2007/10/02)
In the complex , formed between (1-) and phenyl 2-pyridylmethyl sulphoxide (N-SO), the ligand is bound only through the nitrogen and all attempts to induce chelation were unsuccessful.The kinetics of the forward and reverse reactions i
