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[12aS,(+)]-1,2,3,12aβ-Tetrahydro-1-methyl-6,8,9-trimethoxy-12H-[1]benzoxepino[2,3,4-ij]isoquinoline is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

81874-23-9

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81874-23-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 81874-23-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,1,8,7 and 4 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 81874-23:
(7*8)+(6*1)+(5*8)+(4*7)+(3*4)+(2*2)+(1*3)=149
149 % 10 = 9
So 81874-23-9 is a valid CAS Registry Number.
InChI:InChI=1/C20H23NO4/c1-21-10-9-12-5-7-15(22-2)19-17(12)14(21)11-13-6-8-16(23-3)20(24-4)18(13)25-19/h5-8,14H,9-11H2,1-4H3

81874-23-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name (+)-sarcocapnine

1.2 Other means of identification

Product number -
Other names sarcocapnine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:81874-23-9 SDS

81874-23-9Relevant academic research and scientific papers

ALKALOIDS OF SARCOCAPNOS CRASSIFOLIA SUBSP. SPECIOSA

Castedo, Luis,Lopez, Susana,Lera, Angel Rodriguez De,Villaverde, Carmen

, p. 251 - 258 (2007/10/02)

Thirty-four benzylisoquinoline alkaloids were isolated from the aerial parts of Sarcocapnos crassifolia subsp. speciosa.Twenty-seven of them were identified as the following known alkaloids.Benzophenanthridines: 8-hydroxymethyl dihydrosanguinarine, (+)-chelidonine and oxysanguinarine.Ribasines: (+)-ribasine.Aporphinoids: (+)-glaucine, (+)-N-methyl laurotetanine, (+)-isoboldine, O-methyl atheroline and corunnine.Morphinandienones: (-)-pallidine and (+)-salutaridine. 1-Benzylisoquinolines: (+)-crassifoline.Protopines: protopine.Protoberberines: (-)-scoulerine.Cularines and related compounds: (+)-cularine, (+)-cularidine, (+)-celtisine, (+)-breoganine, (+)-sarcocapnidine, (+)-claviculine, oxocularine, oxocompostelline, oxosarcocapnidine, oxosarcophylline, secocularine and secocularidine.Dibenzopyranazepines: (-)-clavizepine.The remainder were seven new cularine-type alkaloids which we named (+)-enneaphylline, (+)-sarcophylline, (+)-norsarcocapnidine, oxocularidine, secosarcocapnidine, norsecocularidine and norsecosarcocapnidine.Their structures have been elucidated by spectroscopic and chemical methods. - Keywords: Sarcocapnos crassifolia subsp. speciosa; Fumariaceae; alkaloid content of aerial parts; 1-benzylisoquinoline alkaloids; novel cularines.

NEW ISOQUINOLINE ALKALOIDS FROM CORYDALIS CLAVICULATA

Guinaudeau, Helene,Allais, Daovi P.

, p. 107 - 111 (2007/10/02)

The alkaloids (+)-crassifoline (6), (+)-claviculine (9) and (+)-norcularidine (12) have been obtained from Corydalis claviculata. (+)-Crassifoline possesses the S configuration at C-1.The phenolic groups in (+)-claviculine are at C-7 and C-3'. (+)-Norcularidine is a new natural product.

NEW PHENOLIC ISOCULARINE AND BENZYLISOQUINOLINE ALKALOIDS AND THEIR BIOGENETIC RELATIONSHIP

Boente, J.M.,Castedo, L.,Cuadros, R.,Lera, A. Rodriguez de,Saa, J.M.,et al.

, p. 2303 - 2306 (2007/10/02)

The first three phenolic isocularines and the first diphenolic 7,8,3',4'-tetraoxygenated tetrahydrobenzylisoquinoline were isolated from Sarcocapnos crassifolia.A pathway for the biogenesis of cularine is considered.

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