81897-71-4Relevant articles and documents
ADDITIONS DIPOLAIRES-1,3 EN SERIE GERMANIEE: ACTION DE NITRILIMINES, OXYDES DE NITRILE, ET NITRONES SUR LES GERMANONES ET GERMATHIONES
Lavayssiere, Helene,Satge, Jacques,Barrau, Jacques,Traore, Moussa
, p. 335 - 348 (2007/10/02)
A new aspect of the reactivity of germanone and germathiones towards nitrilimines, nitriloxides and nitrones is investigated.The regioselectivity of the dipolar 1,3-cycloaddition reactions between germanones or germathiones and diphenylnitrilimine is discussed.The structure of the adducts is determined from chemical or spectroscopic studies (13C NMR, IR).Germa-oxa- or -thia-diazolines, germaoxathiazoles and germaoxathiazolidines are obtained and the thermal stability of these adducts reported.