81904-01-0Relevant articles and documents
SYNTHESIS APPLICATIONS OF AZA-COPE REARRANGEMENTS; A STEREOSELECTIVE SYNTHESIS OF 9a-ARYLHYDROLILOLIDINES ALKALOIDS
Overman, Larry E.,Sworin, Michael,Bass, Lawrence S.,Clardy, Jon
, p. 4041 - 4045 (2007/10/02)
A "Mannic-directed" 2-azonia--sigmatropic rearrangement is the key step in a new, completely stereoselective, method for preparing 9a-arylhydrolilolidines.Specifically, cis-fused bicyclic aminoalcohols 24 upon treatment with formaldehyde and acid aff