819048-96-9Relevant academic research and scientific papers
Tandem dienyne ring-closing metathesis of alkynyl silaketals for the formation of bicyclic siloxanes
Grimm, Jonathan B.,Otte, Ryan D.,Lee, Daesung
, p. 5508 - 5516 (2007/10/03)
The tandem dienyne ring-closing metathesis of alkynyl silaketals containing two tethered olefins was achieved with second generation Grubbs NHC-ruthenium carbene complex to provide bicyclic siloxanes in good to excellent yield. Silaketals synthesized from
Efficient synthesis of alkynylsilyl ethers and silaketals via base-induced alkynylsilane alcoholysis
Grimm, Jonathan B.,Lee, Daesung
, p. 8967 - 8970 (2007/10/03)
The efficient silylation of alcohols with di- and trialkynylsilanes was achieved under base-catalyzed conditions to afford alkynyl silyl ethers and symmetrical alkynyl silaketals in good yield. A selective alcoholysis of dialkynyl silyl ethers to mixed si
