819082-56-9Relevant academic research and scientific papers
B(C6F5)3-Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes
Zhang, Zi-Yu,Liu, Zhi-Yun,Guo, Rui-Ting,Zhao, Yu-Quan,Li, Xiang,Wang, Xiao-Chen
, p. 4028 - 4032 (2017/03/27)
Catalytic amounts of B(C6F5)3 promote the ring opening and subsequent isomerization of a series of unactivated cyclopropanes to afford terminal olefins in good yields when a hydrosilane and 2,6-dibromopyridine are employed as additives.
Chemo- and regioselective C(sp3)-H arylation of unactivated allylarenes by deprotonative cross-coupling
Hussain, Nusrah,Frensch, Gustavo,Zhang, Jiadi,Walsh, Patrick J.
supporting information, p. 3693 - 3697 (2014/04/17)
The combination of aryl bromides, allylbenzene, base and a palladium catalyst usually results in a Heck reaction. Herein we combine these same reagents, but override the Heck pathway by employing a strong base. In the presence of LiN(SiMe3)sub
Catalytic SN2′-selective substitution of allylic chlorides with arylboronic esters
Whittaker, Aaron M.,Rucker, Richard P.,Lalic, Gojko
supporting information; experimental part, p. 3216 - 3218 (2010/10/02)
(Figure Presented) A copper-catalyzed SN2′-selective arylation of allylic chlorides has been achieved using arylboronic esters as nucleophiles. Arylation products were obtained in high yield with a variety of allylic chlorides and arylboronic e
