81912-09-6Relevant articles and documents
GENERATION OF DIENONE AND TRIENONE DIANION DERIVATIVES; DOUBLE DEPROTONATION AS A ROUTE TO LUMO-FILLED ?-SYSTEMS
Seebach, Dieter,Pohmakotr, Manat
, p. 4047 - 4058 (2007/10/02)
Conjugated unsaturated carbonyl compounds and their analogues 1 are a1,3,5...-reagents.An umpolung of this intrinsic reactivity can be achieved by generation of the dianions 2, LUMO filled ?-systems, from hydrogenated precursors, see schemes 1