81939-86-8

Basic information

• Product Name: trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide
• Synonyms: trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide
• CAS NO: 81939-86-8
• Molecular Weight: 308.442
• Mol File: 81939-86-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide(CAS DataBase Reference)
• NIST Chemistry Reference: trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide(81939-86-8)
• EPA Substance Registry System: trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide(81939-86-8)

Safety Data

• Hazardous Substances Data: 81939-86-8(Hazardous Substances Data)

Upstream product

• 81939-79-9 (2R,6S)-2,6-Dimethyl-cyclohex-3-ene-1,2-diol 
• 81939-75-5 5-methyl-6-(trimethylsiloxy)cyclohex-2-en-1-one 
• 81939-80-2 cis-3,4-dihydroxy-trans-3,5-dimethylcyclohexene 3,4-acetonide 
• 81939-85-7 β-1,2-epoxy-α-cis-3,4-dihydroxy-trans-3,5-dimethylcyclohexane 3,4-acetonide 
• 108-98-5 thiophenol 

Downstream Products

• 81939-83-5 3-[2-((3aR,4R,5R,7R,7aR)-4-Benzenesulfinyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-5-ylsulfanyl)-ethoxy]-cyclopent-2-enone 
• 81939-90-4 Trifluoro-thioacetic acid S-((3aR,4R,5R,7R,7aR)-4-benzenesulfinyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-5-yl) ester 
• 81939-89-1 cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)-1-<(trifluoroacetyl)thio>cyclohexane 3,4-acetonide 
• 81939-92-6 cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylsulfinyl)cyclohexane 3,4-acetonide 
• 81939-88-0 cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylthio)cyclohexane 3,4-acetonide 
• 82769-82-2 trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide 
• 81939-87-9 1-chloro-cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide 
• 82769-90-2 (1'RS,2'RS,3'SR,4'SR,6'RS)-N,N-dimethyl-1-<1-(2,2-dimethyl-1,1-diazanediyl)-2-(2',3'-dihydroxy-2',4'-dimethyl-6'-(phenylsulfonyl)cyclohexyl)ethyl>cyclopropanecarboxamide 2',3'-acetonide 
• 82769-93-5 (1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-<3-(methoxycarbonyl)-2-oxopropyl>cyclohexane-1,2-diol 1,2-diacetonide 
• 82769-91-3 (1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone 
• 82769-92-4 (1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide 
• 82769-83-3 cis-3,4-dihydroxy-trans-3,5-dimethyl-1-(phenylsulfonyl)cyclohexene 3,4-acetonide 
• 82769-85-5 (1'S,1R,2R,3S,4S,6R)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylthio)cyclohexane-1,2-diol 1,2-acetonide 
• 82769-84-4 (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylthio)cyclohexane-1,2-diol 1,2-acetonide 

Relevant articles and documents

Cytochalasin Support Studies. The C14-C19 Subunit of Cytochalasin C. Intramolecular 2 + 2 Photochemical Cycloaddition of Vinyl Sulfones

An intramolecular 2? + 2? photochemical cycloaddition between a six-membered ring vinyl sulfone and a five-membered ring vinylogous ester is described.The process occurs with moderate regiospecificity, the direction being controlled by a cis-acetonide moiety on the six-membered ring.Attempts to fragment the β-alkoxy sulfone adduct to trigger a DeMayo ring expansion were unsuccessful.