81944-40-3Relevant academic research and scientific papers
REGIOSELECTIVE PRENYLATION OF PHENOLS BY PALLADIUM CATALYST: SYNTHESES OF PRENYLPHENOLS AND CHROMANS
Tsukayama, Masao,Kikuchi, Makoto,Kawamura, Yasuhiko
, p. 1487 - 1490 (2007/10/02)
The palladium-catalyzed coupling reaction of iodophenols (1) with 2-methyl-3-butyn-2-ol gave alkynylphenols (2).Catalytic hydrogenation of 2 over Raney nickel and the subsequent dehydration of the resultant alkylphenols (3) gave regioselectively the desired prenylphenols (4).Dehydration of alkylphenols (3f-h) gave chromans (7).
Synthesis of two meroterpenic acetophenones occurring in Senecia and Helianthella species
Sudalai, A.,Rao, G. S. Krishna
, p. 760 - 761 (2007/10/02)
Starting from the common synthon, methyl 3-propanoate (4), the syntheses of two naturally occurring meroterpenes, 4-hydroxy-3-(3'-hydroxyisopentyl)acetophenone (1) and 3-(2-isopenten-1-yl)-4-methoxyacetophenone (3)
