819816-63-2Relevant academic research and scientific papers
Chiral carbanions, part 4: Borylation of (trimethylsilyl)methyl N,N-dialkyl-carbamates - Diastereoselectivity and structural studies
Simov, Biljana Peric,Rohn, Agnieszka,Brecker, Lothar,Giester, Gerald,Hammerschmidt, Friedrich
, p. 2704 - 2710 (2007/10/03)
(Trimethylsilyl)methyl carbamates were prepared from (trimethylsilyl) methanol and N,N-dialkylcarbamoyl chlorides and were metalated by s-BuLi/TMEDA. The configurationally labile lithiated carbamates were reacted with borates derived from (+)-pinane-2,3-d
