819871-36-8Relevant academic research and scientific papers
Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants
Chen, Chun-Hao,Tsai, Yen-Ching,Liu, Rai-Shung
supporting information, p. 4599 - 4603 (2013/05/21)
Golden control: The title reaction (see scheme) proceeds with high stereocontrol to generate the heterocyclic products in good yield. Experiments to probe the mechanism were performed. Copyright
Ruthenium-catalyzed cyclization of epoxide with a tethered alkyne: Formation of ketene intermediates via oxygen transfer from epoxides to terminal alkynes
Madhushaw, Reniguntala J.,Lin, Ming-Yuan,Abu Sohel, Shariar Md.,Liu, Rai-Shung
, p. 6895 - 6899 (2007/10/03)
Treatment of (o-ethynyl)phenyl epoxides with TpRuPPh3(CH 3CN)2PF6 (10 mol %) in hot toluene (100 °C, 3-6 h) gave 2-naphthols or 1-alkylidene-2-indanones very selectively with isolated yields exceeding 72%, depen
