81992-91-8

Upstream product

• 591-50-4 iodobenzene 
• 40137-29-9 2-methyl-4-chlorobenzaldehyde 
• 21143-54-4 2-Benzyl-4-chlorobenzyl alcohol 

Downstream Products

• 21143-53-3 methyl 2-benzyl-4-chlorobenzoate 
• 83562-05-4 N-<4-(2-benzoyl-4-chlorophenyl)-5-cyanothiazol-2-yl>acetamide 
• 83562-04-3 N-<4-(2-benzyl-4-chlorophenyl)-5-cyanothiazol-2-yl>acetamide 
• 83562-06-5 N-(8-chloro-6-phenyl-4H-thiazolo<5,4-d><2>benzazepin-2-yl)acetamide 
• 83562-03-2 2-amino-4-(2-benzyl-4-chlorophenyl)-5-thiazolecarbonitrile 
• 78368-02-2 8-chloro-6-phenyl-4H-thiazolo<5,4-d><2>benzazepin-2-amine 
• 83562-02-1 3-(2-Benzyl-4-chloro-phenyl)-2-bromo-3-oxo-propionitrile 
• 83562-01-0 3-oxo-3-(4-chloro-2-benzylphenyl)propanenitrile 

Relevant academic research and scientific papers

Palladium-catalyzed benzylic C(sp3)–H arylation of o-alkylbenzaldehydes

The palladium-catalyzed benzylic C(sp3)–H arylation of o-alkylbenzaldehyde derivatives was achieved utilizing 2-dimethylaminoethylamine as a novel transient directing group. The γ-C(sp3)–H arylation reaction efficiently afforded a variety of arylated o-alkylbenzaldehydes and polycyclic aromatic hydrocarbons (PAHs) in one pot, exhibiting high functional group tolerance with broad substrate scope. The aliphatic diamine auxiliary represents a simple, inexpensive, readily available, and removable directing group for C–H activation. The resultant o-benzylbenzaldehyde products could be diversely transformed into potentially important synthetic intermediates under mild conditions.

Pyrrolo[3,4-d][2]benzazepinones

The present invention relates to compounds of the formula STR1 wherein R1 and R3 are selected from the group consisting of hydrogen, lower alkyl, hydroxy, lower alkoxy or acyloxy and R2 and R4 are hydrogen or R

2-Benzazepines. 2. Thiazolobenzazepines

As part of a program in the area of annelated 2-benzazepines, several thiazolobenzazepines were prepared.Treatment of the bromo ketones 7-9 with various thio amides gave the thiazoles 10-15, which when treated with methylamine gave the title com

Pyrazolobenzazepines

There are presented compounds of the formulas STR1 wherein R1 is hydrogen or lower alkyl; R2 and R3 are selected from the group consisting of hydrogen, lower alkyl, C2 to C7 carboxylic acids, hydroxy

Pyrrolo[3,4-d][2]benzazepines

The present invention relates to compounds of the formula STR1 wherein R1 is selected from the group consisting of hydrogen, lower alkyl, C3 to C7 alkenyl or alkynyl, hydroxymethyl, the group STR2 wherein R11 is