82005-90-1

Basic information

• Product Name: Chloro-dimethyl-(2-methyl-benzyl)-silane
• CAS NO: 82005-90-1
• Molecular Weight: 198.768
• Mol File: 82005-90-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Chloro-dimethyl-(2-methyl-benzyl)-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Chloro-dimethyl-(2-methyl-benzyl)-silane(82005-90-1)
• EPA Substance Registry System: Chloro-dimethyl-(2-methyl-benzyl)-silane(82005-90-1)

Safety Data

• Hazardous Substances Data: 82005-90-1(Hazardous Substances Data)

Upstream product

• 4342-61-4 1,2-dichlorotetramethylsilane 
• 552-45-4 1-chloromethyl-2-methylbenzene 

Relevant articles and documents

CONVERSION OF DISILANES TO FUNCTIONAL MONOSILANES. XII. THE PALLADIUM(0)-CATALYZED DECHLORINATIVE SILYLATION OF BENZYLIC CHLORIDES WITH METHYLCHLORODISILANES. A FACILE ROUTE TO BENZYLMETHYLCHLOROSILANES

This paper describes the facile dechlorinative silylation of benzylic chlorides of types XC6H4CH2Cl (X = H, Me and Cl) and ClCH2C6H4CH2Cl (o-, m- and p-isomers) with methylchlorodisilanes ClMe2SiSiMe2Cl, ClMe2SiSiMeCl2 and Cl2MeSiSiMeCl2 in the presence of Pd(PPh3)4 to give the corresponding benzylmethylchlorosilanes in good to high yields.