82005-93-4Relevant academic research and scientific papers
Synthesis of silicon-containing macrocyclic compounds by using intramolecular [2+2] photocycloaddition reactions of bis-dimethylsilyl-linked styrenes and stilbenes
Maeda, Hajime,Nishimura, Ko-ichi,Hiranabe, Ryu-ichiro,Mizuno, Kazuhiko
, p. 472 - 477 (2018)
A method for the synthesis of silicon-containing macrocyclic compounds, using intramolecular [2 + 2] photocycloaddition reactions of bis-dimethylsilyl-linked styrene or stilbene derivatives, is described. Photoirradiation of benzene solutions of o- and m-
Intramolecular photocycloaddition of β-stilbazoles tethered by silyl chains
Maeda, Hajime,Hiranabe, Ryu-ichiro,Mizuno, Kazuhiko
, p. 7865 - 7869 (2007/10/03)
Intramolecular (2+2) photocycloaddition of β-stilbazoles tethered by silyl chains took place with high efficiency. Complexation with dicarboxylic acid or catechol further enhanced both the efficiency and stereoselectivity.
Synthesis and photochemical properties of stilbenophanes tethered by silyl chains. Control of (2π + 2π) photocycloaddition, cis-trans photoisomerization, and photocyclization
Maeda, Hajime,Nishimura, Ko-Ichi,Mizuno, Kazuhiko,Yamaji, Minoru,Oshima, Juro,Tobita, Seiji
, p. 9693 - 9701 (2007/10/03)
Novel macrocyclic and medium-size stilbenophanes tethered by silyl chains were synthesized, and their photochemical and photophysical properties were examined. Direct photoirradiation of macrocyclic stilbenophanes gave intramolecular photocycloadducts ste
CONVERSION OF DISILANES TO FUNCTIONAL MONOSILANES. XII. THE PALLADIUM(0)-CATALYZED DECHLORINATIVE SILYLATION OF BENZYLIC CHLORIDES WITH METHYLCHLORODISILANES. A FACILE ROUTE TO BENZYLMETHYLCHLOROSILANES
Matsumoto, Hideyuki,Kasahara, Miyuki,Matsubara, Ikuya,Takahashi, Masatoshi,Arai, Takeshi,et al.
, p. 99 - 108 (2007/10/02)
This paper describes the facile dechlorinative silylation of benzylic chlorides of types XC6H4CH2Cl (X = H, Me and Cl) and ClCH2C6H4CH2Cl (o-, m- and p-isomers) with methylchlorodisilanes ClMe2SiSiMe2Cl, ClMe2SiSiMeCl2 and Cl2MeSiSiMeCl2 in the presence of Pd(PPh3)4 to give the corresponding benzylmethylchlorosilanes in good to high yields.
A CONVENIENT SYNTHESIS OF BENZYLMETHYLCHLOROSILANES BY THE PALLADIUM-CATALYZED DECHLORINATIVE SILYLATION OF BENZYLIC CHLORIDES WITH METHYLCHLORODISILANES
Matsumoto, Hideyuki,Kasahara, Miyuki,Matsubara, Ikuya,Takahashi, Masatoshi,Nakano, Taichi,Nagai, Yoichiro
, p. 399 - 400 (2007/10/02)
Benzylmethylchlorosilanes were prepared in high yields by the dechlorinative silylation of benzylic chlorides with methylchlorodisilanes MenSi2CI6-n (n = 2, 3, and 4) in the presence of a catalytic amount of Pd(PPh3)4.
