82008-23-9Relevant academic research and scientific papers
FERRIDOPORPHYRINES A LIAISON ? METAL-CARBONE: SYNTHESE, CARACTERISTIQUES ET ETUDE DE LA REACTION D'INSERTION DU DIOXYDE DE SOUFRE ENTRE LE FER ET LE GROUPE ALKYL
Cocolios, P.,Laviron, E.,Guilard, R.
, p. C39 - C42 (1982)
Iron(III) porphyrins containing a metal-carbon bond have been prepared, isolated and fully characterized.The insertion of sulphur dioxide into the bond between the iron atom and the alkyl group has been studied.
SYNTHESE ET CARACTERISATION PAR RMN 1H D'ALKYL(ARYL)FERRIPORPHYRINES A LIAISON ? METAL-CARBONE
Cocolios, P.,Lagrange, G.,Guilard, R.
, p. 65 - 80 (2007/10/02)
A series of alkyl(aryl)iron(III) porphyrins with a metal-carbon ? bond has been prepared either by action of an organomagnesium compound on iron(III) chloride porphyrins or by oxidative addition of alkyl halides to iron(I) porphyrins. 1H NMR data have been used to characterize the products obtained.
