82010-28-4

Upstream product

• 138760-83-5 ((1S,2S)-1-Isobutyl-2-trimethylsilanyloxy-but-3-enyl)-carbamic acid tert-butyl ester 
• 421557-33-7 (E)-(S)-4-(tert-Butoxycarbonyl-hydroxymethyl-amino)-6-methyl-hept-2-enoic acid methyl ester 
• 114423-50-6 methyl (E,4S)-4-[(tert-butoxycarbonyl)amino]-6-methylhept-2-enoate 
• 864165-68-4 (E)-(S)-4-(Acetoxymethyl-tert-butoxycarbonyl-amino)-6-methyl-hept-2-enoic acid methyl ester 
• 864165-76-4 (E)-(S)-4-(tert-Butoxycarbonyl-hydroperoxymethyl-amino)-6-methyl-hept-2-enoic acid methyl ester 
• 138760-84-6 ((1S,2S)-4-Hydroxy-1-isobutyl-2-trimethylsilanyloxy-butyl)-carbamic acid tert-butyl ester 
• 339185-93-2 tert-butyl 1-(methoxy(methyl)amino)-4-methyl-1-oxopentan-2-ylcarbamate 
• 91254-81-8 (1-Formyl-3-methylbutyl)carbamic acid,1,1-dimethylethyl ester 

Relevant academic research and scientific papers

Stereoselective vinylation of amino aldehydes using 2-trimethylsilylethylidentriphenylphosphorane

2-Trimethylsilylethylidentriphenylphosphorane reacts stereoselectively with α-amino aldehydes giving the Cram chelation controlled product of vinylation of the carbonyl group. The olefinic 1,2-amino alcohols obtained with this reaction are important inter

Intramolecular nucleophilic epoxidation of γ-amino-α,β- unsaturated esters with an N-hydroperoxymethyl group

Intramolecular nucleophilic epoxidation reactions of γ-amino-α, β-unsaturated esters have been studied for the first time with a hydroperoxymethyl group attached to the nitrogen atom. The epoxidation was fast under mild basic conditions and highly anti se