820233-17-8Relevant academic research and scientific papers
Allylic hydroxy phosphonates: Versatile chiral building blocks
De La Cruz, Antonette,He, Anyu,Thanavaro, Anchalee,Yan, Bingli,Spilling, Christopher D.,Rath, Nigam P.
, p. 2577 - 2592 (2007/10/03)
Allylic hydroxy phosphonates are converted into β and γ substituted amino phosphonates using a series of palladium-catalyzed reactions. The judicious selection of nitrogen nucleophile and palladium catalyst allow for excellent regio- and stereochemical co
Synthesis of nonracemic allylic hydroxy phosphonates via alkene cross metathesis
He, Anyu,Yan, Bingli,Thanavaro, Anchalee,Spilling, Christopher D.,Rath, Nigam P.
, p. 8643 - 8651 (2007/10/03)
Allylic hydroxy phosphonates and their derivatives can be interconverted by using cross metathesis with second generation Grubbs catalyst. The absolute stereochemistry of the starting phosphonate is conserved in the product. Cross metathesis reaction of t
