820243-68-3Relevant academic research and scientific papers
Reactions of [Re(NO)2(PR3)2][BAr F4] complexes with phenylacetylene
Frech,Llamazares,Alfonso,Schmalle,Berke
, p. 1116 - 1120 (2004)
The reaction of [Re(NO)2(PR3)2][BAr F4] (R = cyclo-C6H13 (1a), Pr i (1b); [BArF4]- = [B(3,5-(CF 3)2C6H3)4]) with phenylacetylene in the presence of a non-nucleophilic base, like 2,6-bis(tert-butyl)pyridine (BTBP) or ButOK, affords the phenylethynyl complexes [Re(C≡CPh)(NO)2(PR3) 2] (R = cyclo-C6H13 (2a); Pri (2b)) in moderate yields. In the absence of a base, complexes 1a and 1b are transformed into the compounds [Re(C≡CPh)(CH=C(Ph)ONH)(NO)(PR 3)2][BArF4] (3a and 3b, respectively). The structure of complex 3a was confirmed by X-ray diffraction analysis. The latter reaction is proposed to be initiated by deprotonation of the terminal alkyne H atom by the bent nitrosyl ligand followed by the subsequent 1,3-dipolar addition of the ReN(H)O moiety to phenylacetylene.
