82033-62-3Relevant academic research and scientific papers
The Cyclic Voltammetry and Cathodic Reduction of Steroidal Homoallylic Nitro Esters. Dimerization vs. Cyclopropane Formation
Sato, Takeo,Komeichi, Yoshihisa,Kobayashi, Shoichi,Omura, Akira
, p. 520 - 526 (2007/10/02)
The cathodic reduction of homoallylic nitro esters was carried out in DMF-TBAP using platinum electrodes.The reaction was found to be highly dependent on the ester-leaving group: Whereas 6-nitrocholest-5-en-3β-yl acetate (3a) gave a 3,3'-dimer 4, 3β-tosyl
