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carbonyl(η5-cyclopentadienyl)(dimethylarsino)(dimethylphenylphosphine)iron(II) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

82066-77-1

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82066-77-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 82066-77-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,0,6 and 6 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 82066-77:
(7*8)+(6*2)+(5*0)+(4*6)+(3*6)+(2*7)+(1*7)=131
131 % 10 = 1
So 82066-77-1 is a valid CAS Registry Number.

82066-77-1Upstream product

82066-77-1Relevant academic research and scientific papers

UEBERGANGSMETALL-SUBSTITUIERTE PHOSPHANE, ARSANE UND STIBANE. XXIX METALLIERTE ARSANE UND STIBANE MIT CHIRALEM EISEN-SUBSTITUENTEN

Kaul, Hans-Achim,Greissinger, Dieter,Luksza, Michael,Malisch, Wolfgang

, p. C29 - C35 (1982)

The reaction of Cp(CO)2Fe-EMe2 (E=As,Sb,Bi) with Me3P, Et3P, Me2PhP and (MeO)3P leads to a CO/R3P exchange and formation of the chiral derivatives Cp(CO)(R3P)Fe-EMe2.Cp(CO)Fe-EMe2 rearranges already at room temperature to Cp(CO)Fe-P(O)(OMe)2.The high nucleophilicity of the new organometallic Lewis bases is established by the easy conversion of Cp(CO)(Me3P)Fe-SbMe2 to I with MeI, or to Hal (L = CO, Hal = Cl; L=Me3P, Hal = Br) with Cp(CO)LFe-Hal, respectively.The new compounds are characterized by spectroscopy and elementary analyses.

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