820961-92-0

Basic information

• Product Name: Benzothiazole, 2-[(1,1-dimethyl-3-phenylpropyl)thio]-
• CAS NO: 820961-92-0
• Molecular Formula: C18H19NS2
• Molecular Weight: 313.488
• Mol File: 820961-92-0.mol

Chemical Properties

• CAS DataBase Reference: Benzothiazole, 2-[(1,1-dimethyl-3-phenylpropyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzothiazole, 2-[(1,1-dimethyl-3-phenylpropyl)thio]-(820961-92-0)
• EPA Substance Registry System: Benzothiazole, 2-[(1,1-dimethyl-3-phenylpropyl)thio]-(820961-92-0)

Safety Data

• Hazardous Substances Data: 820961-92-0(Hazardous Substances Data)

Upstream product

• 149-30-4 2-Mercaptobenzothiazole 
• 820961-79-3 1,1-dimethyl-3-phenylpropyl diphenylphosphinite 
• 719-22-2 2,6-Di-tert-butyl-1,4-benzoquinone 
• 103-05-9 4-phenyl-2-methyl-2-butanol 

Downstream Products

• 79399-18-1 benzyl (2-methyl-4-phenyl)but-2-yl sulphide 

Relevant articles and documents

A new type of oxidation-reduction condensation by the combined use of phenyl diphenylphosphinite and oxidant

A new type of oxidation-reduction condensation of alcohols with sulfur, nitrogen, and oxygen nucleophiles by the combined use of phenyl diphenylphosphinite (PhOPPh2) and oxidants such as azides or diethyl azodicarboxylate (DEAD) are described. In these reactions, chiral secondary and tertiary alcohols are converted into the corresponding chiral sulfides, azides, esters and ethers under mild and neutral conditions with almost complete inversion of stereochemical configuration.

Conversion of alcohols to alkyl aryl sulfides by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite

Preparation of alkyl aryl sulfides from alcohols and arenethiols such as 2-sulfanyl-1,3-benzothiazole (BtzSH) is described by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite (PhOPPh 2) and benzoquinone derivatives or azide compounds. This reaction proceeds under mild and neutral conditions and is applicable to the thioetherification of various alcohols in which the chiral secondary and tertiary alcohols are converted into the corresponding chiral sulfides with almost complete inversion of configuration.

Stereospecific C-S bond formation from chiral tertiary alcohols by quinone-mediated oxidation-reduction condensation using alkyl diphenylphosphinites and its application to the synthesis of a chiral tertiary thiol

Oxidation-reduction condensation between 2-sulfanyl-1,3-benzothiazole (Btz-SH) and the alkyl diphenylphosphinites 1, prepared from tertiary alcohols, proceeded smoothly in the presence of 2,6-di-t-butyl-1,4-benzoquinone (DBBQ) and the corresponding S-alky

Preparation of tert-Alkyl aryl sulfides from tert-alcohols via quinone-mediated oxidation-reduction condensation between tert-Alkyl diphenylphosphinites and 2-sulfanyl-1,3-benzothiazole

A convenient two-step procedure for the construction of sulfur-containing quaternary centers from tert-alcohols involving chiral ones is established. tert-Alkyl diphenylphosphinites 1 were easily prepared in excellent yields from tert-alcohols and ClPPhs

A new method for the preparation of alkyl aryl sulfides from alcohols via alkoxydiphenylphosphines by oxidation-reduction condensation

A new method for the preparation of alkyl aryl sulfides from alcohols via alkoxydiphenylphosphines by oxidation-reduction condensation was established. Various primary, secondary, and tertiary alcohols were successfully converted into the corresponding su