82104-66-3

Basic information

• Product Name: N-Phenyl-4-bromophthalimide
• Synonyms: 4-Bromo-N-phenylphthalimide;5-Bromo-2-phenyl-1H-isoindole-1,3(2H)-dione;N-Phenyl-4-bromophthalimide;5-bromo-2-phenylisoindoline-1,3-dione
• CAS NO: 82104-66-3
• Molecular Formula: C₁₄H₈BrNO₂
• Molecular Weight: 302.12282
• Mol File: 82104-66-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Phenyl-4-bromophthalimide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Phenyl-4-bromophthalimide(82104-66-3)
• EPA Substance Registry System: N-Phenyl-4-bromophthalimide(82104-66-3)

Safety Data

• Hazardous Substances Data: 82104-66-3(Hazardous Substances Data)

Usage

General Description

N-Phenyl-4-bromophthalimide is a chemical compound with the formula C14H8BrNO2. It is a white to off-white solid that is often used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. It is also used as a building block in organic synthesis, particularly in the production of dyes and pigments. N-Phenyl-4-bromophthalimide is a versatile compound with potential applications in various industries, making it an important chemical in the field of organic chemistry.

Upstream product

• 86-90-8 4-bromophthalic anhydride 
• 108-91-8 cyclohexylamine 
• 34598-49-7 5-Bromo-1-indanone 
• 62-53-3 aniline 

Downstream Products

• 1438667-00-5 5-(2-bromopyridin-3-ylamino)-2-phenylisoindoline-1,3-dione 
• 82104-34-5 (Z)-5,5'-Dibromo-2,2'-diphenyl-[1,1']biisoindolylidene-3,3'-dione 
• 82104-41-4 3-benzyl-6-bromo-3-hydroxy-1-isoindoline 
• 82104-22-1 6-Bromo-2-phenyl-3-[(E)-phenylimino]-2,3-dihydro-isoindol-1-one 
• 51256-60-1 3-benzylidene-6-bromo-2-phenyl-1-isoindoline 
• 82104-15-2 5-Bromo-2-phenyl-isoindole-1,3-dithione 
• 82104-07-2 6-Bromo-2-phenyl-3-thioxo-2,3-dihydro-isoindol-1-one 
• 73819-74-6 N-phenyl-4-ethynylphthalimide 

Relevant articles and documents

Confined photoactive substructures on a chiral scaffold: The design of an electroluminescent polyimide as material for PLED

The optical and electroluminescent properties of a new chiral electroluminescent polyimide consisting of alternating conjugated segments and chiral units is described. The synthesized polymer exhibited high thermal stability (Td = 350°C), high electron af

Organic electroluminescence material and organic photoelectric device

The invention provides a compound with a structure as shown in formula I. The invention also provides an application of the compound in an organic photoelectric device and the organic photoelectric device. The compound provided by the invention has a thermal activation delayed fluorescence (TADF) material luminous mechanism, can be used as a novel TADF material applied to the field of the organic photoelectric device and can increase the illuminating efficiency. No expensive metal complex is used by the compound provided by the invention; the manufacturing cost is low; the application prospect is wider.

Cuprous Oxide Catalyzed Oxidative C-C Bond Cleavage for C-N Bond Formation: Synthesis of Cyclic Imides from Ketones and Amines

Selective oxidative cleavage of a C-C bond offers a straightforward method to functionalize organic skeletons. Reported herein is the oxidative C-C bond cleavage of ketone for C-N bond formation over a cuprous oxide catalyst with molecular oxygen as the oxidant. A wide range of ketones and amines are converted into cyclic imides with moderate to excellent yields. In-depth studies show that both α-C-H and β-C-H bonds adjacent to the carbonyl groups are indispensable for the C-C bond cleavage. DFT calculations indicate the reaction is initiated with the oxidation of the α-C-H bond. Amines lower the activation energy of the C-C bond cleavage, and thus promote the reaction. New insight into the C-C bond cleavage mechanism is presented.