82108-68-7Relevant academic research and scientific papers
Reactions involving Transition Metals. Part 15. Reactions of Alkyl an Acyl-peroxy-anions with (1+) (M= Ir or Rh)
Bird, Christopher,Booth, Brian L.,Haszeldine, Robert N.
, p. 517 - 522 (2007/10/02)
The title compounds react with peroxycarboxylic acids RCO3H in the presence of NEt3 to give the compounds (L = PPh3), which, with MeI, give and (R = C6H4Cl-m, Ph, or Me).Reaction between NaO2COR' (R' = C6H4Cl-m) and (1+) affords an inseparable mixture of , , and ; under similar conditions the rhodium analogue gives a mixture of and .Reactions between NaO2But and either (1+) or give only .
