82111-34-0Relevant academic research and scientific papers
Asymmetric hydrogenation of chiral vinyloxazaborolidines under ambient conditions
Gamsey, Soya,DeLaTorre, Kelly,Singaram, Bakthan
, p. 711 - 715 (2007/10/03)
Novel homochiral vinyloxazaborolidines have been synthesized and subsequently hydrogenated using palladium on carbon under ambient conditions to produce, after oxidation of the boronate group, enantiomerically enriched secondary alcohols (up to 20% ee). H
THE STEREOSELECTIVE REDUCTION OF α-AMINODEOXYBENZOIN DERIVATIVES WITH SODIUM BOROHYDRIDE
Alcaide, Benito,Escobar, Gerardo,Gonzalez-Simo, Jose L.,Lopez-Mardomingo, Carmen,Perez-Ossorio, Rafael,Plumet, Joaquin
, p. 2033 - 2036 (2007/10/02)
Total stereoselectivity is observed in the sodium borohydride reduction of α-aminodeoxybenzoins and their hydrochlorides in various hydroxylic solvents.RS-SR isomer (erythro) was the only aminoalcohol obtained.
