82154-72-1Relevant academic research and scientific papers
1-ACETOXY-2-CYCLOHEXENE OXIDATION IN THE PRESENCE OF MOLYBDENUM, VANADIUM AND CHROMIUM COMPOUNDS
Bandurko, Valentina,Gudimenko, Yurii,Shingel, Igor,Agabekov, Vladimir,Mitskevich, Nikolai
, p. 173 - 184 (2007/10/02)
A study has been made on the catalytic oxidation of ACH-2 with molecular oxygen.The composition of reaction products (1-acetoxy-2-cyclohexene-4-one, 1-acetoxy-2-cyclohexene-4-ol) and their formation pathway have been analyzed.In MoO2(acac)2 catalysis, 1-acetoxy-2,3-epoxycyclohexane is formed. In an ACH-2 medium, the catalytic HP-decomposition mechanism and reaction yields have been investigated.The HP-decomposition have been shown to proceed through intermediate complexes over catalysts with the following overall decomposition rate constants: The hydroperoxide decomposes mainly heterolytically in the presence of MoO2(acac)2.With Cr(acac)2 the radical decomposition fraction amounts to under 1percent.
