82194-10-3Relevant academic research and scientific papers
THE OXIME REARRANGEMENT CYCLIZATION. ALKENYL, STYRYL AND VINYL CHLORIDE TERMINATORS IN THE SYNTHESIS OF Δ1-PYRROLINES
Gawley, Robert E.,Termine, Enrico J.
, p. 307 - 308 (1982)
Functionalized γ,δ-unsaturated oximes, constructed by regiospecific alkylation of appropriate oximes, may be rearranged and cyclized to Δ1-pyrrolines in good yield.
Synthesis and photoisomerization of rhodopsin-based molecular switches
Blanco-Lomas, Marina,Campos, Pedro J.,Sampedro, Diego
, p. 6328 - 6334,7 (2020/09/16)
A new family of switches based on a rhodopsin chromophore is presented. These new photoswitches fulfil most of the required features for an efficient switch to be used in practical applications. The synthetic route is simple and versatile and enables substituents capable of acting as anchoring points to be incorporated. Also, substitution can be used to fine tune the switches' properties. The photostationary state can be reached easily by using low-energy light compatible with complex environments. Thermal reset allows these switches to operate through on/off cycles.
The Oxime Rearrangement Cyclization. Synthesis of Alkylidene-Δ1-pyrrolines
Gawley, Robert E.,Termine, Enrico J.
, p. 1946 - 1951 (2007/10/02)
Appropriately functionalized alkenyl oximes cyclize to Δ1-pyrrolines when treated with trimethylsilyl polyphosphate (PPSE) in refluxing CCl4.The reaction is stereospecific, and the reaction conditions do not cause oxime isomerization at a rate
