82201-30-7Relevant academic research and scientific papers
A NEW AND FACILE PERHYDROAZULENE FORMATION: THE TOTAL SYNTHESIS OF THE CAROTANE (+)-DAUCENE
Audenaert, Frans,Keukeleire, Denis De,Vandewalle, Maurits
, p. 5593 - 5604 (2007/10/02)
Thermolysis of the 2,5-bis(trimethylsiloxy)tricyclo2,5>decan-7-ones 3 leads to perhydroazulenes by a transannular reaction involving an oxygen to oxygen migration of a silyl group in the intermediate cyclodecadienones.This 3-step transf
A NEW AND FACILE HYDROAZULENE FORMATION : EVIDENCE FOR THE THERMAL OXYGEN TO OXYGEN MIGRATION OF A TRIMETHYLSILYL GROUP
Audenaert, Frans,Vandewalle, Maurits
, p. 4521 - 4524 (2007/10/02)
Thermolysis of the 2,5-bis(trimethylsiloxy)-tricyclo2,5>decan-7-ones 3 and 16 leads to hydroazulenes by a transannular reaction involving a remarkable oxygen to oxygen migration of a silylgroup in the intermediate cyclodecadienones.
