82201-48-7Relevant academic research and scientific papers
SILICON IN ORGANIC SYNTHESIS. 12. trans-1-BENZENESULFONYL-2-(TRIMETHYLSILYL)ETHYLENE, A DIELS-ALDER DIENOPHILE EQUIVALENT OF ACETYLENE AND MONOSUBSTITUTED ACETYLENES
Paquette, Leo A.,Williams, Richard V.
, p. 4643 - 4646 (2007/10/02)
trans-1-Benzenesulfonyl-2-(trimethylsilyl)ethylene and its 1,2-d2 derivative enter into Diels-Alder cycloaddition to give products which are smoothly eliminated with fluoride ion.Alkylation of the α-sulfonyl carbanion can precede elimination, s
