82231-35-4

Upstream product

• 100-44-7 benzyl chloride 
• 709-50-2 methyl beta-D-glucopyranoside 
• 19488-61-0 methyl 2,3,4,6-tetra-O-benzyl α-D-glucopyranoside 

Downstream Products

• 82231-34-3 methyl 3-O-acetyl-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 152338-98-2 Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester 
• 116142-78-0 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-tetrahydro-pyran-4-yl ester 
• 10378-06-0 2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[1,2-d]-2-oxazoline 
• 35303-87-8 methyl 3-O-acetate-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 152369-58-9 C₆₂H₇₂O₁₉ 
• 152339-00-9 (2S,3R,4S,5S,6R)-2-[(2S,3R,4R,5S,6S)-3,5-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-4-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 152369-56-7 C₅₁H₅₈O₁₀ 
• 152369-57-8 methyl 2,4,6-tri-O-benzyl-3-O-(2,4-di-O-benzyl-α-L-rhamnopyranosyl)-β-D-glucopyranoside 
• 152338-99-3 methyl-3-O-(3-O-allyl-4-O-benzyl-α-L-rhamnopyranosyl)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Regioselective de-O-benzylation of monosaccharides

Poly-O-benzylated sugars are regioselectively debenzylated using CrCl2/LiI in moist EtOAc. A predictive, three-point coordination model is proposed.

A Study of the Rapid Anomerization of Poly-O-benzyl-β-D-glucopyranosides with Titanium Tetrachloride

Titanium tetrachloride rapidly anomerizes methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside in dichloromethane at 25 deg C.Evidence for the proposal that the benzyloxymethyl group on C-5 and the ring oxygen of the glucoside cooperate to prompt the reaction is described.The reagent anomerizes the interglycosidic linkage of several disaccharide derivatives.