82231-39-8

Upstream product

• 4356-80-3 methyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 74-88-4 methyl iodide 
• 6988-40-5 methyl 2,3-di-O-benzyl-β-D-glucopyranoside 
• 100-44-7 benzyl chloride 

Downstream Products

• 57783-72-9 methyl 2,3,4-tri-O-benzyl-6-O-methyl-α-D-glucopyranoside 
• 5155-50-0 Methyl-(6-O-methyl-β-D-glucopyranosid) 

Relevant academic research and scientific papers

A Study of the Rapid Anomerization of Poly-O-benzyl-β-D-glucopyranosides with Titanium Tetrachloride

Titanium tetrachloride rapidly anomerizes methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside in dichloromethane at 25 deg C.Evidence for the proposal that the benzyloxymethyl group on C-5 and the ring oxygen of the glucoside cooperate to prompt the reaction is described.The reagent anomerizes the interglycosidic linkage of several disaccharide derivatives.