82235-28-7

Upstream product

• 15174-47-7 α-methyl-trans-cinnamaldehyde 
• 399513-43-0 (+/-)-(1E)-2-(1-methyl-2-phenyl-vinyl)-oxirane 
• 100-44-7 benzyl chloride 
• 82235-23-2 2-[2-Methyl-3-phenyl-2-(toluene-4-sulfonyl)-propyl]-[1,3]dioxolane 

Downstream Products

• 874196-27-7 C₆H₅CH₂C₂H₃CHCHOHCH₂CH₃ 
• 874196-29-9 C₆H₅CH₂C₂H₃NHCO₂CH₃CHCHCH₂CH₃ 
• 874196-30-2 C₆H₅CH₂C₂H₃NHCO₂CH₃CH₂OH 
• 874196-32-4 C₆H₅CH₂C₂H₃NHCO₂CH₃CO₂H 
• 874196-28-8 C₆H₅CH₂C₂H₃CHCHCH₂CH₃OCONH₂ 
• 17350-84-4 (R)-2-amino-2-methyl-3-phenylpropanoic acid 

Relevant academic research and scientific papers

Microwave-assisted organic acid-base-co-catalyzed tandem Meinwald rearrangement and annulation of styrylepoxides

A novel organic acid-base-co-catalyzed conversion of styrylepoxides into [1,1′-biaryl]-3-carbaldehydes was realized under microwave irradiation. Styrylepoxides first underwent an acid-catalyzed Meinwald rearrangement followed by a tandem base-catalyzed Michael addition, aldol addition, and aromatization sequence to generate [1,1′-biaryl]-3-carbaldehydes.

A NEW PROCEDURE FOR DESULFONYLATION: PREPARATION OF β-SUBSTITUTED α,β-UNSATURATED KETONES AND ALDEHYDES

The treatment of the tert-alkyl sulfones bearing carbonyl group at the β-position with 5 percent hydrochloric acid in THF at 30 - 65 deg C afforded β-substituted α,β-unsaturated ketones and aldehydes in excellent yields.