82238-71-9Relevant academic research and scientific papers
CYCLOADDITION OF SINGLET OXYGEN AND TRIAZOLINEDIONE (TAD) WITH SPIROCYCLOPENTADIENYL-1,3,5-CYCLOHEPTATRIENES: TROPILIDENE VERSUS NORCARADIENE REACTIVITY
Adam, Waldemar,Rebollo, Hector,Duerr, Heinz,Pauly, Karl-Heinz,Peters, Karl,et al.
, p. 923 - 926 (1982)
4-Methyl-1,2,4-triazoline-3,5-dione (MTAD) gives with 7-spirofluorenyl-1,3,5-cycloheptatriene (1d) initially the norcaradiene-type urazole (N3d) which at ambient temperatures rearranges into (6d), while 1O2 gives the tropilidene-type endoperoxide (T4d).
