82274-79-1Relevant academic research and scientific papers
THE CONFIGURATIONS OF BENZYLMETHYL(o- OR p-TOLYL)SILYLMETHYLAMINE AND THE STEREOCHEMISTRY OF THE REACTIONS OF BENZYLMETHYLMETHOXYPHENYLSILANE WITH SOME ORGANOMETALLIC AGENTS
Terunuma, Daiyo,Senda, Kazuhisa,Sanazawa, Masato,Nohira, Hiroyuki
, p. 924 - 927 (2007/10/02)
Optically active α-amino organosilanes such as benzylmethyl(o- or p-tolyl)silylmethylamine were converted into benzylmethylphenyl(o- or p-tolyl)silane, of which the configurations had been known.From these observations, it was found that (+)- and (-)-benzylmethyl(o- or p-tolyl)silylmethylamine has S and R configuration respectively.Furthermore, the stereochemistry of the reaction of benzylmethyl(methoxy)phenylsilane with some organometallic agents was investigated.
