82296-97-7

Basic information

• Product Name: Benzene, [(2-ethylpentyl)sulfinyl]-
• CAS NO: 82296-97-7
• Molecular Formula: C13H20OS
• Molecular Weight: 224.367
• Mol File: 82296-97-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-ethylpentyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-ethylpentyl)sulfinyl]-(82296-97-7)
• EPA Substance Registry System: Benzene, [(2-ethylpentyl)sulfinyl]-(82296-97-7)

Safety Data

• Hazardous Substances Data: 82296-97-7(Hazardous Substances Data)

Upstream product

• 4050-45-7 trans-2-hexene 
• 40110-39-2 lithilated phenyl methyl sulfoxide 

Relevant articles and documents

170. Asymmetric Palladium-Assisted Alkylation of Alkenes

Palladium-promoted alkylation of alkenes using chiral sulfoxide-containing carbanions and chiral lithiated oxazolines results in asymmetric induction (AI) ranging from 3-5 percent (1,5 induction), 20-40 percent (1,3 induction) to 44-52 percent (1,4 induction).No general trend allowing predictions of results was found.With 1-hexene, attack at C(1) is almost exclusive but propene gives a mixture of attack at C(1) and C(2).The use of a chiral ligand together with malonate anion also leads to some asymmetric induction (ca. 20 percent).