82299-14-7Relevant academic research and scientific papers
Heterogeneously catalyzed one-pot synthesis of aldimines from primary alcohols and amines by supported ruthenium hydroxides
Kim, Jung Won,He, Jinling,Yamaguchi, Kazuya,Mizuno, Noritaka
, p. 920 - 921,2 (2009)
The one-pot synthesis of aldimines from primary alcohols and amines via sequential reactions of alcohol oxidation and dehydrative condensation could efficiently be promoted by supported ruthenium hydroxide catalysts, in particular Ru(OH)x/TiO2. The observed catalysis was truly heterogeneous and the retrieved catalyst could be reused without an appreciable loss of high catalytic performance. Copyright
193. Photoformation of (Z)-Isomers in Diarylazomethines. Part IV. Direct and Sensitized Photoisomerization of Pyridyl Analogues of Benzylidene-aniline and Absorption Spectra of their (Z)-Isomers
Maeda, Koko,Fischer, Ernst
, p. 1961 - 1965 (2007/10/02)
UV irradiation of solutions of the (E)-isomers of five (out of the possible six) monopyridyl analogues at reduced temperatures results in extensive (80-90percent) conversion into the corresponding (Z)-isomers.The process is reversible both thermally and photochemically.The (Z)-isomers are stable at temperatures below -80 deg, and their absorption spectra were estimated.Biacetyl-photosensitized (E)->(Z) isomerization was observed, with (Z)-contents of ca. 70percent at the photostationary state.
