82316-08-3Relevant academic research and scientific papers
Cyclization of aryl acyl radicals generated from S-(4-cyano)phenyl thiolesters by a nickel complex catalyzed electroreduction
Ozaki, Shigeko,Adachi, Masashi,Sekiya, Sayaka,Kamikawa, Rie
, p. 4586 - 4589 (2007/10/03)
Aromatic acyl radicals generated from S-(4-cyano)phenyl 2-alkenylthiobenzoate by a nickel complex catalyzed electroreduction undergo 5- and 6-exo cyclization to give 1-indanone and dihydro-1-naphthalenone derivatives, respectively.
Intramolecular addition reactions of functionalized arylcarbenes to double bonds
Kirmse, Wolfgang,H?mberger, Günter
, p. 3925 - 3934 (2007/10/02)
Arylcarbenes with unsaturated ortho substituents (vinyloxy, 1-propenyloxy, allyl, 2-butenyl, 2,4-pentadienyl) were generated in methanol by photolysis of diazo precursors. Intermolecular OH insertion was found to compete with intramolecular addition to th
