82316-71-0

Basic information

• Product Name: 1-bromo-3-dichlorophosphinoyladamantane
• Synonyms: 1-bromo-3-dichlorophosphinoyladamantane
• CAS NO: 82316-71-0
• Molecular Weight: 332.004
• Mol File: 82316-71-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bromo-3-dichlorophosphinoyladamantane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-3-dichlorophosphinoyladamantane(82316-71-0)
• EPA Substance Registry System: 1-bromo-3-dichlorophosphinoyladamantane(82316-71-0)

Safety Data

• Hazardous Substances Data: 82316-71-0(Hazardous Substances Data)

Upstream product

• 876-53-9 1,3-dibromoadamantane 

Relevant articles and documents

Phosphorylation of Adamantane and its Derivatives in Trifluoroacetic Acid Medium

The possibility of dichlorophosphorylation of the carcass compounds of the adamantane series and of aryl(alkyl)carbinols, with phosphorus trichloride in the low-nucleophilicity trifluoroacetic acid medium was first demonstrated. A new preparative method for introducing a POCl2 group into the bridgehead and bridge positions of the adamantane nucleus, as well as into the α position of the side chain was developed. Some intermediate adamantyl cations may undergo isometizations, among them skeleton ones. A mechanism of the phosphorylation was proposed.