82316-74-3Relevant articles and documents
Phosphorylation of Adamantane and its Derivatives in Trifluoroacetic Acid Medium
Shokova,Erokhin,Kovalev
, p. 1624 - 1634 (2007/10/03)
The possibility of dichlorophosphorylation of the carcass compounds of the adamantane series and of aryl(alkyl)carbinols, with phosphorus trichloride in the low-nucleophilicity trifluoroacetic acid medium was first demonstrated. A new preparative method for introducing a POCl2 group into the bridgehead and bridge positions of the adamantane nucleus, as well as into the α position of the side chain was developed. Some intermediate adamantyl cations may undergo isometizations, among them skeleton ones. A mechanism of the phosphorylation was proposed.
PHOSPHORYLATED ADAMANTANES. III. INFLUENCE OF A PHOSPHORYL GROUP ON THE REACTIVITY OF THE ADAMANTANE NUCLEUS
Yurchenko, R. I.,Voitsekhovskaya, O. M.,Pinchuk, A. M.,Lavrova, E. E.,Yurchenko, A. G.
, p. 489 - 492 (2007/10/02)
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