82316-74-3Relevant academic research and scientific papers
Phosphorylation of Adamantane and its Derivatives in Trifluoroacetic Acid Medium
Shokova,Erokhin,Kovalev
, p. 1624 - 1634 (2007/10/03)
The possibility of dichlorophosphorylation of the carcass compounds of the adamantane series and of aryl(alkyl)carbinols, with phosphorus trichloride in the low-nucleophilicity trifluoroacetic acid medium was first demonstrated. A new preparative method for introducing a POCl2 group into the bridgehead and bridge positions of the adamantane nucleus, as well as into the α position of the side chain was developed. Some intermediate adamantyl cations may undergo isometizations, among them skeleton ones. A mechanism of the phosphorylation was proposed.
SYNTHESIS AND MASS SPECTRA OF ADAMANTYLPHOSPHORYL DERIVATIVES
Duddeck, Helmut,Elgamal, M. Hani A.,Hanna, Atef G.
, p. 307 - 314 (2007/10/02)
The syntheses of 25 phosphorylated adamantane derivatives are described and their mass spectra are discussed.
