82345-98-0Relevant academic research and scientific papers
Chemistry of Metal-Diene Complexes: 31P NMR Studies of the Reaction of (COD)PtCl2 with Tertiary Phosphines in Methanol
Goel, Anil B.,Goel, Sarla
, p. 141 - 144 (2007/10/02)
Reactions of (COD)PtCl2 with tertiary phosphine ligands in methanol have been studied by 31P nmr spectroscopy.The formation of cationic complex +Cl-, (L = Pri3P, Ph2ButP, But2MeP, Cy3P and But3P) as the only product in the equimolar reaction between (COD)PtCl2 and tertiary phosphines has been defined.In the reaction of (COD)PtCl2 with two mole equivalent of tertiary phosphines, formation of various intermediate complexes including by the nucleophilic attack of methoxyl-anion on the coordinated cyclo-octadiene has been observed.
