82363-25-5

Basic information

• Product Name: 1-(3,4-dimethoxyphenyl)-N-(4-ethoxyphenyl)methanimine
• CAS NO: 82363-25-5
• Molecular Formula: C₁₇H₁₉NO₃
• Molecular Weight: 285.33766
• Mol File: 82363-25-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(3,4-dimethoxyphenyl)-N-(4-ethoxyphenyl)methanimine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3,4-dimethoxyphenyl)-N-(4-ethoxyphenyl)methanimine(82363-25-5)
• EPA Substance Registry System: 1-(3,4-dimethoxyphenyl)-N-(4-ethoxyphenyl)methanimine(82363-25-5)

Safety Data

• Hazardous Substances Data: 82363-25-5(Hazardous Substances Data)

Upstream product

• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 156-43-4 4-Ethoxyaniline 

Relevant articles and documents

Synthesis of novel N-(4-ethoxyphenyl) azetidin-2-ones and their oxidative N-deprotection by ceric ammonium nitrate

It is shown that the N-(p-ethoxyphenyl) group on β-lactams can be oxidatively removed by ceric ammonium nitrate in good yield. Fourteen new N-(p-ethoxyphenyl)-2-azetidinones 8a-n were synthesized through standard [2+2] ketene-imine cycloadditions (Staudinger reaction). Treatment of these compounds with ceric ammonium nitrate yielded the N-dearylated 2-azetidinones 9a-n in good to excellent yields. The effects of solvent, molar equiv of CAN and different temperatures have been investigated and optimum conditions were established.