82366-86-7Relevant academic research and scientific papers
Oxidation of 4-Chromanones with Thalium(III) Nitrate
Ciattini, Pier Giuseppe,Morera, Enrico,Ortar, Giorgio
, p. 395 - 400 (2007/10/02)
Treatment of 4-chromanones 1a-g with thalium(III) nitrate in acidic methanol results mainly in dehydrogenation, whereas α-methoxylation and/or Taylor-McKillop rearrangement predominante in trimethyl orthoformate.The mechanistic features of these oxidations are briefly discussed.
