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CAS

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823786-32-9

trans-[iron(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)ethane]] tetrafluoroborate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 823786-32-9 Structure

  • Basic information

    1. Product Name: trans-[iron(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)ethane]] tetrafluoroborate
    2. Synonyms:
    3. CAS NO:823786-32-9
    4. Molecular Formula:
    5. Molecular Weight: 1028.48
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 823786-32-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: trans-[iron(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)ethane]] tetrafluoroborate(CAS DataBase Reference)
    10. NIST Chemistry Reference: trans-[iron(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)ethane]] tetrafluoroborate(823786-32-9)
    11. EPA Substance Registry System: trans-[iron(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)ethane]] tetrafluoroborate(823786-32-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 823786-32-9(Hazardous Substances Data)

823786-32-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 823786-32-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,2,3,7,8 and 6 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 823786-32:
(8*8)+(7*2)+(6*3)+(5*7)+(4*8)+(3*6)+(2*3)+(1*2)=189
189 % 10 = 9
So 823786-32-9 is a valid CAS Registry Number.

823786-32-9Upstream product

823786-32-9Downstream Products

823786-32-9Relevant articles and documents

Synthesis and characterization of the first examples of dicationic dihydrogen complexes of iron and ruthenium with the PF3 ligand

Nanishankar,Nethaji, Munirathinam,Jagirdar, Balaji R.

, p. 3048 - 3056 (2007/10/03)

New dicationic dihydrogen complexes of the type trans-[M(η2- H2)(PF3)(diphosphane)2]2+ [M = Ru, diphosphane = dppm (Ph2PCH2PPh2); M = Fe, Ru, diphosphane = dppe (Ph2PCH2CH2PPh2)] have been prepared from the precursor hydrides trans-[M(H)(PF 3)(diphosphane)2]+ upon reaction with HOTf. In the case of dppm, in addition to the trans-dihydrogen complex cis-[Ru(η2-H2)(PF3)(dppm)2] 2+ was also obtained in the protonation reaction. The intact nature of the H-H bond in these derivatives has been established using the spin-lattice relaxation time measurements (short T1 values) and the large J H,D coupling constant of the H-D isotopomers. The H-H bond lengths and the stabilities of the dihydrogen complexes are discussed in terms of the π-acidity of the PF3 ligand and compared with other systems possessing trans CO and CNH ligands. The trans-[Ru(η2-H 2)(PF3)(dppe)2]2+ complex was found to be remarkably stable with respect to the loss of bound H2 for a period of about 16 h. The H-D isotopomer of this complex exhibits small temperature variations in the JH,D coupling constant. The X-ray crystal structure of trans-[Ru(H)(PF3)(dppm)2][BF 4] has been determined. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

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