823787-29-7Relevant academic research and scientific papers
Palladium-catalyzed intramolecular O-arylation of enolates: Application to benzo[6]furan synthesis
Willis, Michael C.,Taylor, Dawn,Gillmore, Adam T.
, p. 4755 - 4757 (2004)
(Chemical Equation Presented) A catalyst generated from Pd 2(dba)3 and the ligand DPEphos effects intramolecular C-O bond formation between enolates and aryl halides in the conversion of 1-(2-haloaryl)ketones directly into the corres
Palladium-catalyzed tandem alkenyl and aryl C-N bond formation: A cascade N-annulation route to 1-functionalized indoles
Willis, Michael C.,Brace, Gareth N.,Holmes, Ian P.
, p. 403 - 406 (2007/10/03)
(Chemical Equation Presented) A single tandem operation allows rapid access to a variety of substituted N-functionalized indoles. The nitrogen atom of the indole nucleus is incorporated through Pd-catalyzed aryl and alkenyl C-N bond-forming reactions (see scheme; dba = dibenzylideneacetone). Amine, aniline, amide, carbamate, and sulfonamide functional groups can be introduced efficiently.
