82385-81-7Relevant academic research and scientific papers
AZO AND AZOXY COMPOUNDS. VIII. SYNTHESIS OF 1-OXIDO-2-ALKOXYDIAZENYLALKYLACETIC ESTERS BY NITROSATION OF ALKYLMALONIC ESTERS
Yandovskii, V. N.,Doshchechkina, T. I.,Tselinskii, I. V.,Kuznetsov, V. S.
, p. 427 - 431 (2007/10/02)
Methyl 1-oxido-2-alkoxydiazenylalkylacetates were isolated during the nitrosation of dimethyl alkylmalonates with nitric oxide followed by treatment with alkylating agents.Alkyl 1-oxido-2-alkoxydiazenylalkylacetates were isolated by treatment of the reaction mixtures formed during the nitrosation of dimethyl alkylmalonates with water and then with alkylating agents.
AZO AND AZOXY COMPOUND. VII. SYNTHESIS AND PROPERTIES OF DERIVATIVES OF 1-OXIDO-2-ALKOXYDIAZENEACETIC ACIDS
Yandovskii, V. N.,Kuznetsov, V. S.,Tselinskii, I. V.,Frolova, G. M.
, p. 445 - 450 (2007/10/02)
The reaction of nitric oxide with malonic ester and subsequent hydrolysis of the reaction mixture led to the disodium salt of N-nitrosohydroxylaminoacetic acid, the alkylation of which gave 1-oxido-2-alkoxydiazeneacetates.The reaction of these esters (alkylation at the carbon atom, hydrolysis, amidolysis, hydrazinolysis) were investigated.
