82386-31-0Relevant academic research and scientific papers
Synthesis of fluoroalkanesulfonyl azides and their reactions as fluoroalkanesulfonyl nitrene precursors
Zhu, Shi-Zheng
, p. 6503 - 6504 (1992)
Thermolysis or photolysis of the title compounds with cyclohexane, Me2C = CMe2, methyl sulfide and triphenyl phosphine gave the corresponding insertion or addition products via the perfluoroalkanesulfonyl nitrene intermediate.
Synthesis and Reactions of Fluoroalkanesulfonyl Azides and N,N-Dichlorofluoroalkanessulfonamides
Zhu, Shi-Zheng
, p. 2077 - 2082 (2007/10/02)
Thermolysis or photolysis of fluoroalkanesulfonyl azides RFSO2N3 afforded the corresponding nitrene intermediates RFSo2N which reacted readily with alkanes, alkenes, benzene, dimethyl sulfide, dimethyl sulfoxide, pyridine and triphenylphosphine to give insertion or addition products.Similar results were obtained by the reactions of N,N-dichlorofluoroalkanesulfonamides, RFSO2NCl2, with the same reagents in the presence of zinc powder.Treatment of RFSO2NCl2 with alkene in the absence of zinc powder gave only a 1:1 adduct via a free-radical intermediate RfSO2NCl.
2-METHOXY- AND 2-POLYHALOGENOMETHOXYTETRAFLUOROETHANESULFONIC ACIDS AND THEIR DERIVATIVES
Volkov, N. D.,Nazaretyan, V. P.,Yagupol'skii, L. M.
, p. 454 - 459 (2007/10/02)
Convenient methods are developed for the synthesis of derivatives of 2-methoxy- and 2-polyhalogenomethoxytetrafluoroethanesulfonic acids.The latter are quite stable compounds and do not differ in their properties from less readily available derivatives of perfluoroalkanesulfonic acids.
